In the capital, Alvaro Morata will look for a successful return to Real Madrid after his re-signing from Juventus. Barcelona are looking for their third straight title Last season's title challengers and Champions League runners-up Atletico Madrid also get underway, taking on newly-promoted Alaves at the Vicente Calderon on Sunday at 9. As they prepare for their last season at their famous home before moving to Estadio La Peineta, Diego Simeone's side welcome striker Kevin Gameiro and midfielder Nico Gaitan to the side. Real Madrid have not won the title since "I tipped Atletico when they won it and I have tipped them ever since, for the last two seasons they haven't delivered, but I am going to stick with them," he said on the first La Liga Weekly Podcast of the season. Atletico Madrid prepare for their final season at the Vicente Calderon Viewers can watch matches outside 3pm Saturday blackout hours every week via Sky Sports TV channels, the red button and Sky's digital TV channel, Sky Sports Xtra, which is available to customers through skysports.
As part of a newly-announced batch of fixtures for February, Sky Sports will show even more of the biggest games featuring 14 different teams - including Louis van Gaal's United at Stamford Bridge and Manuel Pellegrini's Manchester City at home to Tottenham Hotspur.
A mouthwatering selection also includes - unless either side reaches the Capital One Cup Final - the Merseyside derby between Liverpool and Everton at Anfield.
The matches are part of an unrivalled schedule of sport through the festive period and into , with live England Test cricket from South Africa, the William Hill World Darts Championship on the recently announced Sky Sports Darts channel, and the Capital One Cup semi-finals.
Sky Sports head of football Gary Hughes said: "Sky Sports is the only place to see all the stories of an increasingly unpredictable Premier League season, with drama every weekend.
Louis van Gaal and Arsene Wenger will do battle at Old Trafford at the end of February, live on Sky Sports "By March, there will still be 41 Premier League games to come on Sky Sports, and we will be the place to see the thrilling climax to a fantastic season.